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Understanding the stability of carbonates in the lower mantle

Schematic cartoon showing the different forms of carbon inside the Earth; Images of run products of high-pressure experiments in a multi-anvil press; diamond anvil cell used to access the pressure and temperature conditions of the Earth’s mantle.
Photo: nach Stagno et al (2019); Lelia Libon
Schematic cartoon showing the different forms of carbon inside the Earth; Images of run products of high-pressure experiments in a multi-anvil press; diamond anvil cell used to access the pressure and temperature conditions of the Earth’s mantle.

Lately, carbonates have been suspected to be major minerals responsible for transportation of carbon from the Earth’s surface to its deep interior. Understanding their stability and their chemical interactions at great depths is critical for understanding the storage capacity and fluxes of carbon into the Earth interior. Since only few, tiny samples of the Earth’s lower mantle get to the surface, we need to simulate pressure (Gigapascals) and temperature (≥ 1500 K) conditions of the Earth’s interior, using hydraulic multi-anvil presses and diamonds anvil cells. From the results, mineral phases and their composition, observed in these experiments we will expand our knowledge on the Deep Carbon Cycle.

Schematic cartoon showing the different forms of carbon inside the Earth; Images of run products of high-pressure experiments in a multi-anvil press; diamond anvil cell used to access the pressure and temperature conditions of the Earth’s mantle.
Photo: nach Stagno et al (2019); Lelia Libon
Schematic cartoon showing the different forms of carbon inside the Earth; Images of run products of high-pressure experiments in a multi-anvil press; diamond anvil cell used to access the pressure and temperature conditions of the Earth’s mantle.

X-ray fluorescence and X-ray absorption spectroscopy studies of element redistribution processes between carbonates and mantle phases at lower mantle conditions

DFG project, research unit FOR 2125 CarboPat: K. Appel (European XFEL Hamburg) & M. Wilke

Lelia Libon & Max Wilke